@CharAznableLoNZ is the "Compilation" box checked in the tags? If it is, that song will go to the "Various Artists" folder no matter what the Album Artist field says. I've sometimes had an issue where the Compilation box will be inexplicably checked on albums where the artist is the same on every song--very annoying but thankfully pretty easy to fix.
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RE: Album Synced to Various Artists Folder Incorrectly.